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CAS.3975-77-7 1-BROMO-2,4,6-TRI-TERT-BUTYLBENZENE

CAS.3975-77-7 1-BROMO-2,4,6-TRI-TERT-BUTYLBENZENE
CAS.3975-77-7  1-BROMO-2,4,6-TRI-TERT-BUTYLBENZENE

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Product Name: 1-BROMO-2,4,6-TRI-TERT-BUTYLBENZENE
Synonyms: 1-BROMO-2,4,6-TRI-TERT-BUTYLBENZENE 97+%;Bromo(1,3,5-tris-tert-butyl)benzene;NSC 133894;2,4,6-Tri-tert-butylphenyl bromide;1-BroMo-2,4,6-tri-tert-butylbenzene 97%;Bromobenzene, 2,4,6-tri-tert-butyl-;1-BROMO-2,4,6-TRI-TERT-BUTYLBENZENE;Benzene, 2-bromo-1,3,5-tris(1,1-dimethylethyl)-
CAS: 3975-77-7
MF: C18H29Br
MW: 325.33
EINECS:  
Product Categories: Aryl;C13 to C37+;Halogenated Hydrocarbons
Mol File: 3975-77-7.mol
 
1-BROMO-2,4,6-TRI-TERT-BUTYLBENZENE Chemical Properties
Melting point  168-173 °C (lit.)
Boiling point  299.7±9.0 °C(Predicted)
density  1.064±0.06 g/cm3(Predicted)
storage temp.  Sealed in dry,Room Temperature
BRN  1913257
 
Safety Information
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
 
 
1-BROMO-2,4,6-TRI-TERT-BUTYLBENZENE Usage And Synthesis
Uses 1-Bromo-2,4,6-tri-tert-butylbenzene was used in the synthesis of bulky biarylphosphine ligand. This ligand was reported to participate in the Pd-catalyzed C-O cross-coupling of a wide range of aryl halides and phenols under milder conditions. It was used to investigate the effect on oligomerization of increased steric bulk in dimethylindium(III) chalcogenolates. It may be used to form α,α-dimethyl-β-phenyl hydrostyrene by reacting with phenylboronic acid.
General Description 1-Bromo-2,4,6-tri-tert-butylbenzene (2,4,6-tri-tert-butylbromobenzene) is a hindered aryl bromide. 1-Bromo-2,4,6-tri-tert-butylbenzene on reaction with phenylboronic acid yields α,α-dimethyl-β-phenyl hydrostyrene.
 
1-BROMO-2,4,6-TRI-TERT-BUTYLBENZENE Preparation Products And Raw materials
Raw materials Bromotrichlorosilane-->1,3,5-Tri-tert-butylbenzene-->2,4,6-TRI-TERT-BUTYLANILINE-->3,5-Di-tert-butylbromobenzene-->Trichlorosilane-->Benzene-->Nitric acid-->Acetic acid

 

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